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Wear Metals Testing for Oils and Lubricants

Oil and Lubricant wear metals testing.

The determination of wear metals in used oil is a key diagnostic method used in Oil Condition Monitoring (OCM), Equipment Condition Monitoring (ECM), Condition Based Maintenance (CBM) programs.

Wear Metal Analysis in oils and lubricants allows maintenance to be scheduled efficiently, minimising the risk of damage to expensive plants and avoiding unscheduled downtime and maintenance, helping productivity and avoid costly repair or shut downs.

The Early stage of wear in oils and lubricants significantly improves the reliability of the machinery.

Hence – ATLAS – provides a comprehensive state-of-the-art Oil Testing & Lubricant Analysis Services. The objective is to spot any potential problems before they cause catastrophic failure.

Sources of Wear Metals in Analysis of Oils

The tables given below give an indication of the source of wear metals in the oil. Due to these wear metals, it is possible to identify the components that are wearing.

Wear Metals

Iron

Iron is the dominant and most common of the wear metals. It is found virtually in all equipment in some form or the other. As it is abundantly used it indicates that there are a lot of sources of wear in the machinery.

Due to this knowledge, the testing of this component allows the analyst to distinguish the source of the wear debris, like, cylinder rods vs. bearings.

Iron
Engine Cylinders, Blocks, Gears, Crankshaft, Piston Rings, Camshaft, Valve Train, Oil Pump, Liners
Transmission Gears, Discs, Housing, Bearings, Brake Bands, Shift Spools, Pumps, PTO-Power Take Off
Hydraulic System Pump / Motor Vanes, Gears, Pistons, Cylinder Boxes & Rods, Bearings, Valves, Pump Housing
Gear System Gear, Shafts, Bearings
Compressors Crankshaft Block, Housing, Screws, Bearings, Shaft, Oil Pump, Piston Rings, Cylinders
Turbine Shafts, Gears, Bearings, Valves
Chromium

Chromium is used in machinery and equipment for its resistance to corrosion and for its great strength and hardness. Thus it is found in many systems operating under extreme and harsh conditions.

Chromium
Engine Rings, Roller / Taper, Bearings, Liners, Exhaust Valves, Water Treatment
Transmission Roller / Taper, Bearings, Water Treatment (Oil Cooler)
Hydraulic System Rods, Spools, Roller / Taper, Bearings
Gear System Roller / Taper, Bearings
Compressors Rings, Roller / Taper, Bearings, Water Treatment (Oil Cooler)
Turbine Shafts, Bearings
Copper

Commonly used as an alloy, it is extensively used because of its material properties like excellent electrical and thermal conductivity and is extremely ductile. It is used abundantly in bearing systems and heat exchangers.

Copper
Engine Wrist Pin Bushings, Valve Train, Bushings, Cam Bushings, Bearings (Near Failure), Oil Cooler, Thrust Washers, Governor, Oil Pump, Oil Additives.
Transmission Clutches, Steering Discs, Bushings / Thrust Washers, Oil Cooler
Hydraulic System Pump Thrust Plates, Pump Pistons, Cylinders, Guides, Bushings, Oil Cooler
Gear System Bushings, Thrust Washers
Compressors Wear Plates, Bushings, Wrist Pin Bushings, Bearings, Thrust Washers
Turbine Bearings, Bushings, Thrust Plates, Cooler Core Tubing
Aluminium

Aluminium is prized in equipment because of it's high strength to weight ratio, also it has excellent corrosion resistance. Used as an alloy in combination with other elements it improves its wear and temperature resistance.

Aluminium
Engine Pistons, Bearings, Bushings, Blocks, Housings, Oil Pump Bushings, Blowers, Thrust Bearings
Transmission Pumps, Clutches, Thrust Washer, Bushings
Hydraulic System Pump / Motor, Housing, Cylinder
Gear System Thrust Washers, Oil Pump, Bushings, Some Greases
Compressors Rotors, Pistons, Bearings, Thrust Washers, Block Housing
Turbine Thrust, Heat Exchanger Core, Aluminum Oxides from Silica (Dirt)
Tin

Tin is used as an alloying element along with copper and lead for sacrificial bearing liners.

Tin
Engine Pistons (Overlay), Bearings (Overlay), Bushings
Transmission Roller / Taper, Bearings, Water Treatment (Oil Cooler)
Hydraulic System Rods, Spools, Roller / Taper, Bearings
Gear System Roller / Taper, Bearings
Compressors Rings, Roller / Taper, Bearings, Water Treatment (Oil Cooler)
Turbine Bearings (Babbit), Bushings, Solder from Tin
Lead

A soft metal used for sacrificial wear surfaces such as journal bearings. Lead-based babbits are widely used.

Lead
Engine Bearings, Gasoline, Octane Improver, Oil Additives
Transmission Oil Additives
Hydraulic System Not Found
Gear System Oil Additives
Compressors Bearings
Turbine Bearings, Bushings (Babbit)
Silver

Silver is highly prized as it has the highest electrical as well as thermal conductivity from all metals. It is an excellent bearing plate material, providing minimum friction. Due to its low contact resistance, it is susceptible to corrosive attack.

Silver
Engine Wrist Pin Bushings, Solder From Cooler Core Joints
Transmission Needle Bearings (Traces), Solder From Oil Cooler Core Joints
Hydraulic System Solder, Trace Element
Gear System Not Found
Compressors Solder, Trace Element
Turbine Solder, Trace Element
Cadmium

Cadmium is resistant to corrosion and as a result, it is used as a protective layer when deposited on other metals. Also used as an alloy with certain metals.

Cadmium
Engine Enviornmental Contaminant
Transmission Alloy Metal, Enviornmental Contaminant
Hydraulic System Alloy from Bearings, Enviornmental Contaminant
Gear System Alloy Metal, Enviornmental Contaminant
Compressors Alloy Metal, Enviornmental Contaminant
Turbine Alloy Metal, Enviornmental Contaminant
Vanadium

Used as an Alloy mainly with steel to increase the strength of steel considerably. Used in applications for axles, crankshaft and other critical components.

Vanadium
Engine Alloy Metal, Contaminant in Marine Bunker Fuels
Transmission Not Found
Hydraulic System Alloy Metal
Gear System Not Found
Compressors Alloy Metal
Turbine Alloy Metal
Titanium

The two most important properties of Titanium is corrosion resistance and the highest strength to weight ratio of any metal. Thus it is alloyed with Iron, Molybdenum, Vanadium, aluminium to produce strong lightweight alloys for aero-space, military and industrial use. Also used widely for manufacturing Titanium dioxide used in Paints, Coatings and Pigments.

Titanium
Engine Valves, Piston Pins, Bearings, Shafts
Transmission Shafts, Gears, Bearings, Paint or Coatings
Hydraulic System Valves, Piston Pins, Bearings, Shafts
Gear System Shafts, Gears, Bearings, Paint or Coatings
Compressors Shafts, Gears, Bearings, Paint or Coatings
Turbine Shafts, Gears, Bearings, Paint or Coatings

Contaminant Metals

Silicon

A common contaminant found during lube oil analysis. Mainly due to ingested dirt (sand) which is a very hard crystalline material and is extremely abrasive to metal components. Also found due to Coolant / Anti-freeze and sealant wear.

Silicon
Engine Anti-Foam Additive, Ingested Dirt, Coolant Leak, Silicates from Antifreeze
Transmission Disc Lining, Brake Shoes, Ingested Dirt, Silicates from Antifreeze
Hydraulic System Ingested Dirt, Elastomeric Seals, Silicates from Antifreeze
Gear System Ingested Dirt, Silicone Sealant, Anti-Foam Additive, Silicates from Antifreeze
Compressors Ingested Dirt, Silicone Sealant, Silicates from Antifreeze
Turbine Ingested Dirt, Silicone Sealant, Defoamant Additive, Silicates from Antifreeze
Sodium

Corrosion inhibitor additive also indicates coolant leak into oil, can also be road Salt, Sea water, Ingested Dirt

Sodium
Engine Oil Additive, Anti-Freeze, Salt, Ingested Dirt, Molybdates from some Coolants
Transmission Oil Additive, Anti-Freeze, Salt, Ingested Dirt
Hydraulic System Oil Additive, Anti-Freeze, Ingested Dirt
Gear System Oil Additive, Ingested Dirt
Compressors Oil Additive, Anti-Freeze, Ingested Dirt
Turbine Oil Additive, Anti-Freeze, Ingested Dirt
Potassium

Usually not found in the oil but may be due to coolant leak if associated with Sodium and may be Magnesium.

Potassium
Engine Anti-Freeze, Solder Flux, Head Coatings, Pot-Ash
Transmission Anti-Freeze, Solder Flux, Head Coatings, Pot-Ash
Hydraulic System Airbourne Environmental Contaminant, Anti-Freeze, Solder Flux
Gear System Additive from Potassium or, Sodium Borate Gear Oil, Environmental Contaminant, Solder Flux
Compressors Airbourne Environmental Contaminant, Anti-Freeze, Solder Flux, Gas Contaminant
Turbine Airbourne Environmental Contaminant, Anti-Freeze , Solder Flux, Gas Contaminant
Manganese

Manganese is important for Iron and Steel for its alloying properties as it increases their tensile strength when used. Also when used with Aluminium it increases its resistance against corrosion.

Manganese
Engine Steel Alloy Metal in Gears, Some Shafts
Transmission Steel Alloy Metal in Gears, Some Shafts
Hydraulic System Steel Alloy Metal in Gears, Some Shafts, Bearings
Gear System Steel Alloy Metal in Gears, Some Shafts, Bearings
Compressors Steel Alloy Metal in Gears, Some Shafts, Bearings
Turbine Steel Alloy Metal in Gears, Some Shafts, Bearings

Additive Metals

Boron

Corrosion Inhibitor additive, Antiwear/Antioxidant additive, can indicate coolant leak, grease contamination

Boron
Engine Additive common in Engine Oils and, Gear Oils, Indicates Coolant Leak
Transmission Additive common in Engine Oils and, Gear Oils, Indicates Coolant Leak
Hydraulic System Additive common in Engine Oils and, Gear Oils, Indicates Coolant Leak
Gear System Additive common in Engine Oils and, Gear Oils, Indicates Coolant Leak
Compressors Additive common in Engine Oils and, Gear Oils, Indicates Coolant Leak
Turbine Additive common in Engine Oils and, Gear Oils, Indicates Coolant Leak
Magnesium

Detergent/dispersive additive can also be alloying element in steels

Magnesium
Engine Detergent / Dispersant Additive, Alloy Element in Steels, Environmental Contaminant
Transmission Detergent / Dispersant Additive, Alloy Element in Steels, Environmental Contaminant
Hydraulic System Detergent / Dispersant Additive, Alloy Element in Steels, Environmental Contaminant
Gear System Detergent / Dispersant Additive, Alloy Element in Steels, Environmental Contaminant
Compressors Detergent / Dispersant Additive, Alloy Element in Steels, Environmental Contaminant
Turbine Detergent / Dispersant Additive, Alloy Element in Steels, Environmental Contaminant
Calcium

Detergent/dispersant additive, Alkaline reserve additive for high sulphur fueled engines, can be grease contamination

Calcium
Engine Detergent / Dispersant Additive, Calcium from Water Contamination, Alkaline Reserve Additive
Transmission Detergent / Dispersant Additive, Calcium from Water Contamination, Alkaline Reserve Additive
Hydraulic System Detergent / Dispersant Additive, Calcium from Water Contamination, Alkaline Reserve Additive
Gear System Detergent / Dispersant Additive, Calcium from Water Contamination, Alkaline Reserve Additive
Compressors Detergent / Dispersant Additive, Calcium from Water Contamination, Alkaline Reserve Additive
Turbine Detergent / Dispersant Additive, Calcium from Water Contamination, Alkaline Reserve Additive
Barium

Corrosion Inhibitors, Detergents, Rust inhibitors

Barium
Engine Not Found, Contaminant in Drilling Applications
Transmission Demulsifying Agent in some, Transmission Oils, Contaminant in Drilling Applications
Hydraulic System Demulsifying Agent in some, Transmission Oils, Contaminant in Drilling Applications
Gear System Demulsifying Agent in some, Transmission Oils, Contaminant in Drilling Applications
Compressors Demulsifying Agent, Contaminant in Drilling Applications, Additive common in Compressor, Oils and some Transmission, Fluids and Gear Oils
Turbine Demulsifying Agent, Contaminant in Drilling Applications, Additive common in Compressor, Oils and some Transmission, Fluids and Gear Oils
Phosphorus

Antiwear, Corrosion inhibitors, Anti-oxidants additives, EP additives

Phosphorus
Engine Anti-Wear Additive ZDDP, (Zinc Dialkyl-DithioPhosphate), Phosphate Ester, Phosphate Inhibitor found in Coolants
Transmission Anti-Wear Additive ZDDP, (Zinc Dialkyl-DithioPhosphate), Phosphate Ester, Phosphate Inhibitor found in Coolants
Hydraulic System Anti-Wear Additive ZDDP, (Zinc Dialkyl-DithioPhosphate), Phosphate Ester, Phosphate Inhibitor found in Coolants
Gear System Anti-Wear Additive ZDDP, (Zinc Dialkyl-DithioPhosphate), Phosphate Ester, Phosphate Inhibitor found in Coolants
Compressors EP Additive, Anti-Wear Additive ZDDP, (Zinc Dialkyl-DithioPhosphate), Phosphate Ester, Phosphate Inhibitor found in Coolants
Turbine EP Additive, Anti-Wear Additive ZDDP, (Zinc Dialkyl-DithioPhosphate), Phosphate Ester, Phosphate Inhibitor found in Coolants
Zinc

Antiwear, Corrosion inhibitors, Anti-oxidants, alloying element for bearings, thrust washers, galvanised cases

Zinc
Engine Alloy in Brass, Anti-Wear Additive ZDDP, (Zinc Dialkyl-DithioPhosphate), Galvanized Steel from Filter Cannisters
Transmission Alloy in Brass, Anti-Wear Additive ZDDP, (Zinc Dialkyl-DithioPhosphate), Galvanized Steel from Filter Cannisters
Hydraulic System Alloy in Brass, Anti-Wear Additive ZDDP, (Zinc Dialkyl-DithioPhosphate), Galvanized Steel from Filter Cannisters
Gear System Alloy in Brass, Anti-Wear Additive ZDDP, (Zinc Dialkyl-DithioPhosphate), Galvanized Steel from Filter Cannisters
Compressors Alloy in Brass, Anti-Wear Additive ZDDP, (Zinc Dialkyl-DithioPhosphate), Galvanized Steel from Filter Cannisters
Turbine Alloy in Brass, Anti-Wear Additive ZDDP, (Zinc Dialkyl-DithioPhosphate), Galvanized Steel from Filter Cannisters

Testing of Metals in our Laboratory

Testing of the Metals comprising of Wear Metals, Contaminant Metals and Additive Metals is done in our laboratory.

Equipment used: ICP

Method of Testing: ASTM D5185: Standard Test Method for Determination of Wear Metals and Contaminants in Used Lubricating Oils or Used Hydraulic Fluids

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